{"id":3889,"date":"2019-07-16T12:47:36","date_gmt":"2019-07-16T03:47:36","guid":{"rendered":"http:\/\/163.180.4.222\/lab\/?p=3889"},"modified":"2019-07-16T12:59:40","modified_gmt":"2019-07-16T03:59:40","slug":"a-panoramic-view-of-photodissociation","status":"publish","type":"post","link":"https:\/\/biochemistry.khu.ac.kr\/lab\/?p=3889","title":{"rendered":"A panoramic view of photodissociation"},"content":{"rendered":"<p>&nbsp;<\/p>\n<p>&nbsp;<\/p>\n<p>As light pulses get shorter in time, they correspondingly get broader in frequency. Kobayashi\u00a0<em>et al.<\/em>take advantage of both properties of attosecond pulses to elucidate iodine monobromide (IBr) photodissociation by detecting ultrafast bromine and iodine spectral shifts simultaneously. A preliminary burst of light weakens the I\u2013Br bond. Then, as the atoms fly apart, they reach a configuration where the bond vibration can couple ground and excited electronic states. The broadband probe pulse reveals rapid changes in each atom&#8217;s electronic structure at this juncture.<\/p>\n<p>&nbsp;<\/p>\n<p id=\"p-2\"><em>Science<\/em>, this issue p.\u00a0<a href=\"https:\/\/science.sciencemag.org\/lookup\/doi\/10.1126\/science.aax0076\">79<\/a><\/p>\n<p>&nbsp;<\/p>\n<p>&nbsp;<\/p>\n<p>(\uc6d0\ubb38: <a href=\"https:\/\/science.sciencemag.org\/content\/365\/6448\/40.9?rss=1\">\uc5ec\uae30<\/a>\ub97c \ud074\ub9ad\ud558\uc138\uc694~)<\/p>\n<p>&nbsp;<\/p>\n<p>&nbsp;<\/p>\n<p>&nbsp;<\/p>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>&nbsp; &nbsp; As light pulses get shorter in time, they correspondingly get broader in frequency. Kobayashi\u00a0et al.take advantage of both properties of attosecond pulses to<a href=\"https:\/\/biochemistry.khu.ac.kr\/lab\/?p=3889\" class=\"more-link\">(more&#8230;)<\/a><\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"_monsterinsights_skip_tracking":false,"_monsterinsights_sitenote_active":false,"_monsterinsights_sitenote_note":"","_monsterinsights_sitenote_category":0,"_jetpack_newsletter_access":"","_jetpack_dont_email_post_to_subs":false,"_jetpack_newsletter_tier_id":0,"_jetpack_memberships_contains_paywalled_content":false,"_jetpack_memberships_contains_paid_content":false,"footnotes":"","jetpack_publicize_message":"","jetpack_publicize_feature_enabled":true,"jetpack_social_post_already_shared":true,"jetpack_social_options":{"image_generator_settings":{"template":"highway","default_image_id":0,"font":"","enabled":false},"version":2},"jetpack_post_was_ever_published":false},"categories":[34,36,29,30],"tags":[],"class_list":["post-3889","post","type-post","status-publish","format-standard","hentry","category-lets-do-chemistry","category-lets-do-physics","category-lets-do-science","category-recent-science-news"],"aioseo_notices":[],"jetpack_publicize_connections":[],"jetpack_featured_media_url":"","jetpack-related-posts":[{"id":948,"url":"https:\/\/biochemistry.khu.ac.kr\/lab\/?p=948","url_meta":{"origin":3889,"position":0},"title":"Talking to Pauling\u2019s ghost","author":"biochemistry","date":"June 25, 2018","format":false,"excerpt":"\u00a0 \u00a0 (\uc6d0\ubb38) \u00a0 \u00a0 \u00a0 Nature Chemistry\u00a0volume\u00a010,\u00a0pages\u00a0688\u2013689\u00a0(2018) \u00a0 Michelle Francl dusts off Pauling\u2019s notes on bonding to explore the illusory link between electron promotion and hybridization. \u00a0 \u00a0 Pauling haunts my classes. Metaphorically, and sometimes I suspect, literally. In the fall of 1957, Linus Pauling paid an impromptu visit\u2026","rel":"","context":"In &quot;Essays on Science&quot;","block_context":{"text":"Essays on Science","link":"https:\/\/biochemistry.khu.ac.kr\/lab\/?cat=32"},"img":{"alt_text":"","src":"","width":0,"height":0},"classes":[]},{"id":4917,"url":"https:\/\/biochemistry.khu.ac.kr\/lab\/?p=4917","url_meta":{"origin":3889,"position":1},"title":"Infrared spectroscopy finally sees the light","author":"biochemistry","date":"January 7, 2020","format":false,"excerpt":"\u00a0 \u00a0 The reliance of infrared spectroscopy on light transmission limits the sensitivity of many analytical applications. An approach that depends on the emission of infrared radiation from molecules promises to solve this problem. \u00a0 \u00a0 Atoms in molecules oscillate when irradiated by infrared light. The particular light frequencies that\u2026","rel":"","context":"In &quot;Let's Do Biology!&quot;","block_context":{"text":"Let's Do Biology!","link":"https:\/\/biochemistry.khu.ac.kr\/lab\/?cat=33"},"img":{"alt_text":"","src":"","width":0,"height":0},"classes":[]},{"id":2706,"url":"https:\/\/biochemistry.khu.ac.kr\/lab\/?p=2706","url_meta":{"origin":3889,"position":2},"title":"Changing the gold standard","author":"biochemistry","date":"February 22, 2019","format":false,"excerpt":"\u00a0 \u00a0 Gold \u2014 long presumed to be an inert metal \u2014 has been increasingly shaking this image over the past couple of decades, mostly through electrophilic behaviour. Now, a two-coordinate gold complex has been shown to exhibit nucleophilic reactivity, with the insertion of CO2into its polarized Au\u03b4\u2212\u2013Al\u03b4+\u00a0bond. \u00a0 \u00a0\u2026","rel":"","context":"In &quot;Let's Do Biology!&quot;","block_context":{"text":"Let's Do Biology!","link":"https:\/\/biochemistry.khu.ac.kr\/lab\/?cat=33"},"img":{"alt_text":"","src":"","width":0,"height":0},"classes":[]},{"id":4092,"url":"https:\/\/biochemistry.khu.ac.kr\/lab\/?p=4092","url_meta":{"origin":3889,"position":3},"title":"Making perfectly controlled arrays of molecules at rest","author":"biochemistry","date":"September 18, 2019","format":false,"excerpt":"\u00a0 \u00a0 Since their invention in the early 1970s, optical tweezers have evolved from enabling simple manipulation to applying calibrated forces on\u2014and measuring nanometer-level displacements of\u2014optically trapped objects. Optical tweezers use laser light to create a force trap that can hold nanometer- to micrometer-sized dielectric objects (1). They can noninvasively\u2026","rel":"","context":"In &quot;Let's Do Chemistry!&quot;","block_context":{"text":"Let's Do Chemistry!","link":"https:\/\/biochemistry.khu.ac.kr\/lab\/?cat=34"},"img":{"alt_text":"","src":"","width":0,"height":0},"classes":[]},{"id":2956,"url":"https:\/\/biochemistry.khu.ac.kr\/lab\/?p=2956","url_meta":{"origin":3889,"position":4},"title":"The next step in making arrays of single atoms","author":"biochemistry","date":"March 27, 2019","format":false,"excerpt":"\u00a0 \u00a0 Three studies have demonstrated the cooling and trapping of single strontium and ytterbium atoms in two-dimensional arrays. Such arrays could lead to advances in atomic-clock technology and in quantum simulation and computing. \u00a0 \u00a0 The world around us is made of atoms. There are enormous numbers of them,\u2026","rel":"","context":"In &quot;Let's Do Chemistry!&quot;","block_context":{"text":"Let's Do Chemistry!","link":"https:\/\/biochemistry.khu.ac.kr\/lab\/?cat=34"},"img":{"alt_text":"","src":"","width":0,"height":0},"classes":[]},{"id":2704,"url":"https:\/\/biochemistry.khu.ac.kr\/lab\/?p=2704","url_meta":{"origin":3889,"position":5},"title":"Two are better than one","author":"biochemistry","date":"February 22, 2019","format":false,"excerpt":"\u00a0 \u00a0 Finely tuned interactions in the second coordination sphere of enzymes or homogeneous catalysts can be essential for their function. Now, this concept has been applied to the surface of a catalytic material, utilizing pairs of Cu atoms for the selective electrochemical fixation of CO2. \u00a0 \u00a0 From DNA\u2026","rel":"","context":"In &quot;Let's Do Chemistry!&quot;","block_context":{"text":"Let's Do Chemistry!","link":"https:\/\/biochemistry.khu.ac.kr\/lab\/?cat=34"},"img":{"alt_text":"","src":"","width":0,"height":0},"classes":[]}],"jetpack_sharing_enabled":false,"jetpack_shortlink":"https:\/\/wp.me\/p9Xo1j-10J","_links":{"self":[{"href":"https:\/\/biochemistry.khu.ac.kr\/lab\/index.php?rest_route=\/wp\/v2\/posts\/3889","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/biochemistry.khu.ac.kr\/lab\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/biochemistry.khu.ac.kr\/lab\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/biochemistry.khu.ac.kr\/lab\/index.php?rest_route=\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/biochemistry.khu.ac.kr\/lab\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=3889"}],"version-history":[{"count":1,"href":"https:\/\/biochemistry.khu.ac.kr\/lab\/index.php?rest_route=\/wp\/v2\/posts\/3889\/revisions"}],"predecessor-version":[{"id":3890,"href":"https:\/\/biochemistry.khu.ac.kr\/lab\/index.php?rest_route=\/wp\/v2\/posts\/3889\/revisions\/3890"}],"wp:attachment":[{"href":"https:\/\/biochemistry.khu.ac.kr\/lab\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=3889"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/biochemistry.khu.ac.kr\/lab\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=3889"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/biochemistry.khu.ac.kr\/lab\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=3889"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}